Spatial distribution of PAH concentrations and stable isotope signatures (delta13C, delta15N) in mosses from three European areas - Characterization by multivariate analysis

Autores: Foan, L.; Leblond, S.; Thöni, L.; Raynaud, C.; Santamaría Ulecia, Jesús Miguel; Sebilo, M.; Simon, v.
ISSN: 0269-7491
Volumen: 184
Número: Supl. 1
Páginas: 113 - 122
Fecha de publicación: 2014
Polycyclic aromatic hydrocarbon (PAH) concentrations and N, C stable isotope signatures were determined in mosses Hypnum cupressiforme Hedw. from 61 sites of 3 European regions: Ile-de-France (France); Navarra (Spain); the Swiss Plateau and Basel area (Switzerland). Total PAH concentrations of 100-700 ng g(-1), as well as delta C-13 values of -32 to -29 parts per thousand and delta N-13 values of -11 to -3 parts per thousand were measured. Pearson correlation tests revealed opposite trends between high molecular weight PAH (4-6 aromatic rings) content and delta C-13 values. Partial Least Square regressions explained the very significant correlations (r > 0.91, p < 0.001) between high molecular weight PAH concentrations by local urban land use (<10 km) and environmental factors such as elevation and pluviometry. Finally, specific correlations between heavy metal and PAH concentrations were attributed to industrial emissions in Switzerland and road traffic emissions in Spain.