ARTÍCULO

Sterols Heating: Degradation and Formation of Their Ring-Structure Polar Oxidation Products

Autores: Barriuso Esteban, Blanca; Otaegui-Arrazola, A.; Menendez Carreño, María; Astiasarán Anchía, María Icíar; Ansorena Artieda, Diana María
Título de la revista: FOOD CHEMISTRY
ISSN: 0308-8146
Volumen: 135
Número: 2
Páginas: 706-712
Fecha de publicación: 2012
Lugar: WOS
Resumen:
Cholesterol and phytosterols can be oxidised under heating conditions to give sterol oxidation products (SOPs), known by their toxic effects. This paper studied the degradation of cholesterol and three plant sterols during a 360 min heating treatment (180 degrees C). The formation and further degradation of SOPs was also analysed by GC-MS. Results revealed a sterol susceptibility to degradation according to the following decreasing order: campesterol approximate to beta-sitosterol >= stigmasterol > cholesterol. The degradation curve fit (R-2 = 0.907-0.979) a logarithmic model. SOPs increased their concentration during the first 5-10 min and thereafter, their degradation rate was higher than their formation rate, resulting in a decrease over time. Irrespective of the sterol from which they had derived, 7-keto derivatives presented the highest levels throughout the entire process, and also SOPs with the same type of oxidation followed a similar degradation pattern (R = 0.90-0.99). (C) 2012 Elsevier Ltd. All rights reserved.